Product ID:TRICHLOROFLUOROMETHANE, R11
MSDS Date:01/01/1987
FSC:6830
NIIN:01-040-3656
MSDS Number: BKMYQ

CHEMTRONICS INC

681 OLD WILLETS PATH
HAUPPAUGE, NY 11783
US

Emergency Phone: 516-582-3322

Info Phone: 516-582-3322

Cage: 2M589

CHEMTRONICS INC (CANCELLED USE 21267)

HAUPPAUGE, NY 11760 US

Telephone: 770-424-4888/800-645-5244

Cage: 2M589

TRICHLOROFLUOROMETHANE (CFC-11) (SARA III)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BY INGEST. CONSULT MD IF NEC. DO NOT INDUCE

RTECS: 9999999ZZ

IS A GREATER HAZ THAN ALLOWING IT TO PROGESS

RTECS: 9999999ZZ

CARBONYL HALIDES; CHLORIDES, FLUORIDES, AND

RTECS: 9999999ZZ

CAUTION MAY DISPLACE OXYGEN IN ENCLOSED/CONFINED

RTECS: 9999999ZZ

INDICATED EXCEPT FOR LIFE-SUSTAINING USES

RTECS: 9999999ZZ

NOT A CORR/IRRIT.

RTECS: 9999999ZZ

ALTHOUGH

RTECS: 9999999ZZ

IS TO BE AVOIDED.

RTECS: 9999999ZZ

LD50 LC50 Mixture:ALD:(ORAL RAT)>3725 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:VAP IS HVR/AIR/CAN CAUSE
SUFFOCATION BY REDUCING O*2 AVAIL FOR BRTHG. BRTHG HIGH CONC OF VAP
MAY CAUSE LIGHT-HEADEDNESS/GIDDINESS/SHORTNESS OF BRTH/MAY LEAD TO
NARCOS/CARD IRREGULARITIES/UNCON/D EATH. LC50 RATS 26,200 PPM/4
HRS. NOTE:IN SCREENING TEST W/EXPTL ANIMALS, EXPOS AT APPROX 5000
PPM (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:(V/V)/ABOVE/FOLLOWED BY A LGE IV
EPINEPHRINE CHALLENGE/HAS INDUCED SERIOUS CARD IRREGULARITIES.
CHLOROCARBON/CHLOROFLUOROCARBON (CFC) MATLS HAVE PRDCED SENSIT OF
THE MYOCARDIUM TO EPHINEPHRIN E IN LAB ANIMALS/COULD HAVE A SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (I.E., EPHINEPHRINE) MAY BE
CONTRA-(SEE INGRED 6)
Medical Cond Aggravated by Exposure:SKIN DISEASE:
TRICHLOROFLUOROMETHANE CAN DISSOLVE THE NATURAL OIL OF SKIN,
THEREFORE DERMAT MAY BE EXPECTED TO RESULT FROM RPTD CONT. PERSONS
W/PRE-EXISTING SKIN DISORDERS MAY BE MORE (SEE SUPP DATA)

First Aid:INHAL:REMOVE TO FRESH AIR/CALL MD. IF NOT BRTHG/GIVE ARTF
RESP/PREF MOUTH TO MOUTH. IF BRTHG IS DFCLT/GIVE O*2. DO NOT GIVE
EPINEPHRINE/SIMILAR DRUGS. NOTE TO MD:BECAUSE OF POSS INCRD RISK OF
ELICITIN G CARD DYSRYTHMIAS/CATECHOLAMINE DRUGS/SUCH AS
EPINEPHRINE/SHOULD BE CONSIDERED ONLY AS A LAST RESORT IN LIFE
THREATENING EMER. EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15
MINS. (SEE SUPP DATA)

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:NONFLAMMABLE
Upper Limits:NONFLAMMABLE
Extinguishing Media:NONFLAMMABLE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION MAY OCCUR AT >1100F. THERMAL DECOMPOSITION PRODUCTS
MAY INCLUDE CHLORIDES, FLUORIDES AND PHOSGENE .

Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:AVOID BRTHG VAPS/PRLNGD SKIN EXPOS. USE ONLY IN WELL
VENTD AREAS. NO SMKNG IN AREA OF USE. DO NOT USE IN GEN VICINITY OF
ARC WELDING/OPEN FLAMES/HOT SURF. HEAT/UV RADIA MAY CAUSE FORMATION
OF CHLORIDE S/FLUORIDES/PHOSGENE. (SEE INGRED 5)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:CONSULT LOCAL/SAFETY HEALTH AUTHORITIES IF ADDITIONAL
GUIDANCE IS NECESSARY.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MED CNDTNS:SUSCEPTIBLE TO THE EFFECT OF THIS AGENT. CVS DISEASE:SEE HLT
HAZ/INHAL SECTION. FIRST AID PROC:CALL MD. SKIN:THE COMPOUND IS NOT
LIKELY TO BE HAZ BY SKIN CONT, BUT CLEANSING OF SKIN AFTER U SE IS
ADVISABLE. INGEST: NO SPECIFIC INTERVENTION IS INDICATED AS THE
COMPOUND IS NOT LIKELY TO BE HAZ (SEE INGRED 2)

Boiling Pt:B.P. Text:75.0F,23.9C
Vapor Pres:7.0 (20C)
Vapor Density:4.9
pH:NEUT
Evaporation Rate & Reference:0.1 (CC*4=1)
Solubility in Water:0.1% BY WT @ 77F
Appearance and Odor:CLEAR; SLIGHT ETHEREAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS-POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:CAN BE DECOMP BY HIGH TEMP (OPEN
FLAMES/GLOWING SURF/ETC) FORMING HYDROCHLORIC/HYDROFLUORIC
ACIDS-POSS (SEE INGRED 4)

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . HAZARD SUBSTANCE UNDER CERCLA.

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